ZnO to power the nanogenerators, the first PENG [6]. Ever since there have been many

developments in the output device performance of PENGs, such as the output power density

P

(

)

d and some of these developments are summarized in Table 20.1.

20.3.1.2 TENG

This class of nanogenerators is based on the triboelectric effect. Certain materials are seen

to acquire electric charges after they are separated from a specific material with which it

was in contact. When two triboelectric materials are rubbed against each other, the sur­

face connection increases; hence, the magnitude of triboelectricity [8]. The triboelectric

charges are seen to move to the surface when there is friction between the materials.

When these materials are separated, a potential difference is seen to develop between the

surfaces. The external free electrons usually move to screen the effect of this potential

difference that results in generating an electrical signal [8]. For a triboelectric nanogen­

erator, the output parameters are measured by the following parameters [13]:

V

Qd

S

=

OC

r

(20.3)

I

dQ

dt

Q

I

dt

=

, such that

=

SC

SC

SC

(20.4)

where Q denotes the charge transferred, d is the displacement on sliding the surfaces, S is

the area of the opposite faces, r is the permittivity of the material used in the generation

of the TENG, and t is the time required in a complete cycle. To improve the TENGs’

performance, various polymers have been developed and used to achieve a high output.

TABLE 20.1

The Output Characteristics of PENG and TENG Fabricated Using Various Materials

Device

Materials

Matrix

Output performance

Ref.

VOC [V] Jsc [µA/cm2]

Pd [µW/cm2]

PENG

BaTiO3/carbon tubes

Polydimethylsiloxane

(PDMS)

4.6

1.84 µA

8.8

[ 9]

Graphene quantum dot/

Polyvinylidene Fluoride

(PVDF)

NA

6

25 nA

NA

[ 10]

Polyvinylidene Fluoride

trifluoroethylene P(VDF-

TrFE)/ZnO

NA

61

2.2 µA

NA

[ 11]

BaTiO3/Bacterial cellulose

NA

14

0.19

0.64

[ 12]

TENG

PVDF/Polyethylene

terephthalate (PET)

NA

1140

9.2

NA

[ 8]

Polytetrafluoroethylene

(PTFE)/PMMA

NA

233

3.18

NA

[ 13]

Fluorinated ethylene

propylene (FEP)/Acrylic

NA

1670

13.4

0.016

[ 13]

PDMS/PVA

NA

270.2

0.44

NA

[ 13]

Kapton/PET

NA

191

NA

8.75

[ 8]

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